Showing posts with label chemistry. Show all posts
Showing posts with label chemistry. Show all posts

Tuesday, June 11, 2013

Great Balls of Fire

After learning about gravity and taking the midmorning break,  the Peregrine 3-4 graders and I worked on understanding nuclear fusion in the core of the Sun and where elements come from.

I started by setting the context.  The students had studied atoms and molecules the previous year so I started by drawing a molecule of water (two hydrogen atoms and one oxygen atom) and reminding them of the evidence for atoms and molecules.  Then we zoomed in to one hydrogen atom and discussed the Rutherford experiment showing that atoms are very fluffy; most of their volume is nearly empty while nearly all their mass is concentrated in a tiny volume in the center (nucleus).  Then we zoomed in further by a factor of 10,000 to the nucleus.  For a hydrogen atom, the nucleus is a single positively charged particle called a proton.  I held up a ping-pong ball as a proton and said that if protons really were that size, the atom would have to be the size of South Davis.

To reinforce the sense of scale, I showed the movie Powers of Ten.  This classic ten-minute movie should be seen by anyone wanting to understand the universe.  I also took the time to answer questions about it.

The basic rules of nuclear physics are actually understandable by anyone. Last year we investigated the effects of electrical charge, and concluded that like charges repel while opposite charges attract. Atoms beyond hydrogen in the periodic table have more protons.  But why do the protons stick together if they repel each other? There must be some form of glue.  I demonstrated two magnets  which repelled each other.  They were "donut" magnets threaded onto a rod so they didn't flop around and the repulsion was clear.  But when I turned the rod vertically and one magnet fell with enough speed onto the other one, they touched briefly.  That was enough for the velcro on their surfaces to attach and keep them together.  The velcro is a short-range force, like the strong nuclear force which keeps a nucleus together.

But protons alone can't generate sufficient strong nuclear force to keep nuclei together.  Another type of particle, with similar mass but no charge and called a neutron, provides the glue.  Nuclei need roughly equal amounts of protons and neutrons to be stable.  I modeled this with a bunch of ping-pong balls I had wrapped with velcro.  The "protons" had velcro hooks and the "neutrons" had velcro loops, so that you needed roughly equal numbers of each to build up a large nucleus.  (The different types were also different colors to make the idea plainly visible.)  Adding a neutron to a nucleus adds mass, but doesn't otherwise change the properties of the atom.  For example, a proton plus a neutron is still hydrogen, but we call it a different isotope of hydrogen.  Similarly, carbon-12 (usually written with a superscript 12 on the left) and carbon-14 are different isotopes of carbon which differ by two neutrons.

With that in mind, we can start building up more complicated elements from hydrogen.  Element number 2 (two protons) is helium, and we need two neutrons to provide the glue so the most common isotope of helium is helium-4.   The protons have to be smashed together at very high speed if they are to ever get close enough for the "velcro" of the strong nuclear force to make them stick, so we need very high temperatures to make this fusion process happen. (High temperature means the individual microscopic particles are wiggling or bounding around at high speed.)  We find it difficult to make these high temperatures on Earth, but the core of the Sun is 15 million degrees (Celsius; tens of millions of degrees if you think in Fahrenheit) and this happens quite routinely.  In fact, most stars turn hydrogen into helium in their cores.

Fusing helium into even heavier elements is harder, but most stars will do that as well by the ends of their lives.   It turns out that crashing two heliums together results in an unstable isotope of element 4 (beryllium), which quickly decays back into two helium-4 nuclei. But if you manage to crash a third helium into the two heliums before the two-helium complex has a chance to decay, you make carbon-12 (the most common isotope of element 6, carbon; again, equal amounts of protons and neutrons).  Then, if you crash another helium into that, you get element number 8: oxygen. Another helium into that produces element 10, argon.  These helium capture reactions are common in massive stars (substantially more massive than the Sun), and they create more of the even-numbered elements than the odd-numbered elements (nitrogen, fluorine, etc).  They go all the way up to iron (element 26).  I modeled all this with the velcro-covered ping-pong balls.

Have you noticed what we've done here?  We've explained the origin of the elements using basic, well-understood physical processes. That's pretty cool! Here's a graph of the observed abundances:


You can see that hydrogen is the most abundant, followed by helium, then the even-numbered elements carbon, oxygen....through iron.  But why are there elements beyond iron if stars only make up to iron? Well, stars make up to iron when they are in equilibrium.  But when they explode (a supernova), so much energy is released that even more complicated nuclei can be made.  I won't explain the details here, but the abundances of all the elements beyond iron are well understood as consequences of supernovae.  That we can understand all the features of the above plot is, to me, one of the most amazing things in all of science.

The supernova explosions are also what throw the newly-manufactured elements back into space, where they can mix into gas clouds that eventually collapse to form new stars. That means that the atoms in your body were once inside another star.  (Not from the Sun, because new atoms made in the Sun won't escape until the end of its life.)

Supernovae make some unstable elements, like uranium.  The most common type of decay for a heavy element is to violently eject a "bullet"  made of two protons and two neutrons, in other words a helium nucleus (again I modeled this with the ping-pong balls).  This is why there is helium on Earth; our gravity is too weak to hold on to helium gas, but helium produced by radioactive decays is trapped in rocks underground.  When we drill for natural gas, we can capture some of this helium and eventually use it to fill balloons.  When it escapes from the balloon, it eventually escapes into space.

Big Bang 

I left out one detail in the story above: most of the helium in the plot was actually made in the Big Bang.  Some of the kids had expressed interest in the Big Bang previously, so I used the remaining time to talk about that.  I used the usual balloon-with-stickers demo, and I also showed this interactive tool made by an undergraduate student of mine. The point of the tool is to show that although we see all galaxies moving away from us, observers in all other galaxies also see all galaxies moving away from them. So we are not at the center of anything. If we think back in time, all galaxies were closer to each other, so the universe was denser (and hotter).  Far enough back in time, the universe was so hot (everywhere) that a fair amount of hydrogen fused into helium.  This is called Big Bang nucleosynthesis (BBN). We can look at the abundance of various  BBN byproducts, like hydrogen-2 (aka deuterium) and confirm that this really happened.

Wrapping up

Most of this trimester we worked on understanding the immense size of space.  If this makes you feel insignificant, remember that you are made of atoms from another star.  You are a part of the universe which can actually understand itself


Sunday, December 2, 2012

It's a Gas

Last Friday I discussed solids, liquids and gases with the 1-2
graders.  I brought in samples of each to provide a basis for
discussion.  In addition to the obvious (a wood block, a glass of
water, a balloon filled with air), I brought some things designed to
stimulate their thinking: a rubber band, a cloth, a balloon filled
with water, and sand.  We took about 35 minutes to discuss how we
could define solid, liquid, and gas.  It's not as obvious as you might
think at first; for example, if liquids and gases flow unlike solids,
why can you pour sand?  Does that mean sand is a liquid?  I wish I had
time to document our discussion here!  I'll just document that at the
end it is important to note that substances can change from one state
to another and back depending on the temperature.  Water is the best
example: we talked about glaciers, lakes and rivers, and rain, which
they have already studied this year.  But it's worth mentioning other
examples lest they think this is peculiar to water.  The metal parts
of their desks were once liquid, which was poured into a mold.

In the hour after snack break, we did a more extensive experiment.  I
handed out cups with (small amounts of) vinegar, and they wrote down
observations: it smells funny, it's liquid, etc.  They did the same
with cups of (small amounts of) baking soda.  They also weighed both
cups on the scale together.  I found it easier to use a kitchen scale
which read grams rather than a scientific scale which reads to a
hundredth of a gram, so that I didn't have to explain decimal points.
Then they mixed the two and observed the reaction.  They drew it and
wrote down their observations.  Then we observed what was left: it
smelled different, and it weighed less (typically by a few grams out
of about 100 to start with).  We figured out together where the
missing grams went: when the bubbles popped, the gas escaped (in the
earlier session we had talked about this with respect to balloons).

They did all of the above in small groups (individuals, actually,
because we had three adults and four kids!), but we spent a few
minutes at the end summarizing what we learned.  One child wrote on
his worksheet "V [vinegar] +B [baking soda] = air" so that was a great
place to start discussing.  Did we know that gas was air?  What else
was produced?  They seemed to not recognize that what was left in the
cup was also a result of the reaction and should go on the right hand
side of the equation.  Is the stuff left in the cup just leftover
vinegar and baking soda?  No, because it smelled different.  The
equation written by the child was a great insight, but by the end we
produced a more accurate equation with more words.

Finally, it is important to note that this is a chemical reaction: we produced
some new kinds of substances! This is very much unlike water going
from liquid to gas, which they might have in mind as a model
transformation of a substance.  Because some of them like explosions,
I related it to the chemical reactions in explosions.  Explosions (ok,
most explosions) are chemical reactions too; they just happen faster
and give off more heat.

Then the kids spent 5-10 minutes drawing a scene with as many
different solids, liquids, and gases as they could think of, labeling
each.  At the very end, I rewarded them with a show of Diet Coke and
Mentos fountains.  It was raining, so I bought 1-liter bottles whose
fountains could be contained in the sink.  This turned out to be a
great capstone for the morning, as carbonation seemed to be a new idea
to many of the kids.  We tasted the Diet Coke before and after
defizzing to see the effect of gas on our taste buds.  We also
discussed how the gas was in the liquid and normally comes out slowly
(you can see small bubbles coming out when the cap is off) but comes
out quickly with the help of Mentos.

For those who want more: Here is an entertaining video of Diet Coke and
Mentos reactions.  If you want to go beyond entertainment and learn more
about why it happens, you should watch the Mythbusters episode on Diet
Coke and Mentos.  They do experiments with different ingredients to figure
out what is most responsible for the reaction.